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- W2054343208 abstract "A structural evolution from SrFeO 2.5 (brownmillerite) to SrFeO 3 (perovskite) upon electrochemical oxidation has been systematically studied by in-situ and ex-situ X-ray Diffraction (XRD) and X-ray absorption spectroscopy (XAS). According to the XRD analysis, the orthorhombic SrFeO 2.5 has been gradually converted to the cubic SrFeO 3 as the reaction proceeds. The mostly oxidized perovskite could be been obtained after 66 h, From the in-situ and ex-situ Fe K-edge XANES study, it has been found that the degree of oxidation goes to a maximum after 48 h and 30 h for the bulk and the surface, respectively. EXAFS results are also consistent with the above findings from the fact that no peak evolution could be observed after 48 h and 30 h for both ex-situ and in-situ studies, respectively." @default.
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- W2054343208 date "1997-03-01" @default.
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- W2054343208 title "In-Situ and Ex-Situ Fe K-Edge X-Ray Absorption Spectroscopic Studies for the Structural and Electronic Evolution of Strontium Ferrite upon Electrochemical Oxidation" @default.
- W2054343208 doi "https://doi.org/10.1051/jp4:19971135" @default.
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