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• W2054370892 abstract "Crosslinked poly(4-vinylbenzyl chloride) (PVBC) microspheres of about 550 μm in diameter were first synthesized by suspension copolymerization of 4-vinylbenzyl chloride (VBC) in the presence of a crosslinking agent, ethylene glycol dimethacrylate (EGDMA). Subsequent surface-initiated atom transfer radical polymerization (ATRP) of 4-vinylpyridine (4VP), using the VBC units of PVBC on the microsphere surface as the macroinitiators, produced well-defined (nearly monodisperse) and covalently tethered poly(4-vinylpyridine) (P4VP) brushes. Quaternization of the tertiary amine groups of the P4VP brushes with hexyl bromide gave rise to a high concentration of quaternary ammonium salt (QAS) on the microsphere surfaces. The chemical composition of the microsphere surfaces at various stages of surface modification was characterized by X-ray photoelectron spectroscopy (XPS). The bactericidal effect of the QAS-functionalized microspheres on Escherichia coli (E. coli) was demonstrated. No significant loss in the surface bactericidal activity of the microsphere was observed during repeated applications." @default.
• W2054370892 created "2016-06-24" @default.
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• W2054370892 date "2006-04-01" @default.
• W2054370892 modified "2023-10-06" @default.
• W2054370892 title "POLYMER MICROSPHERES WITH PERMANENT ANTIBACTERIAL SURFACE FROM SURFACE-INITIATED ATOM TRANSFER RADICAL POLYMERIZATION OF 4-VINYLPYRIDINE AND QUATERNIZATION" @default.
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• W2054370892 doi "https://doi.org/10.1142/s0218625x06008220" @default.
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