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• W2054387835 startingPage "1841" @default.
• W2054387835 abstract "The reaction of Ge[N(SiMe3)2]2 with calix[6]arene furnishes a novel macrocyclic product having two divalent germanium atoms incorporated into a Ge2NO rhombus which contains a μ2-oxygen atom and a μ2-NH2 group. The crystal structure of the product indicates the presence of a conformationally rigid molecule where three of the six oxygen atoms of the calix[6]arene are bound to the germanium atoms while the remaining three have been converted into –OSiMe3 or unusual –OSi(H)(NH2)2 groups. Spectral (1H, 13C, and 29Si NMR) data in solution are consistent with the solid-state structure and indicate the germanium calix[6]arene retains its structure in solution." @default.
• W2054387835 created "2016-06-24" @default.
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• W2054387835 date "2008-05-01" @default.
• W2054387835 modified "2023-10-11" @default.
• W2054387835 title "Synthesis and crystal structure of a germanium(II) calix[6]arene containing unusual diamidosilyl ether groups" @default.
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• W2054387835 doi "https://doi.org/10.1016/j.poly.2008.02.027" @default.
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