Matches in SemOpenAlex for { <https://semopenalex.org/work/W2054398465> ?p ?o ?g. }
Showing items 1 to 60 of
60
with 100 items per page.
- W2054398465 endingPage "282" @default.
- W2054398465 startingPage "276" @default.
- W2054398465 abstract "The Schmidt reaction has been carried out on thiochroman-4-one 1-oxide and a number of related sulfoxides. In all cases lactam formation by attack of HN 3 on the carbonyl group of the keto sulfoxide appears to predominate, with no evidence for sulfoximine formation. The question of aryl vs. alkyl migration, as in other systems, is dependent on the degree of substitution of the alkyl group. When the Schmidt reaction was carried out upon thiochromone 1,1-dioxide two products, the lactam resulting from preferential vinyl migration and a novel α-azido sulfone resulting from 1,4-addition, were obtained." @default.
- W2054398465 created "2016-06-24" @default.
- W2054398465 creator A5040910872 @default.
- W2054398465 creator A5076158897 @default.
- W2054398465 creator A5088363184 @default.
- W2054398465 date "1975-01-15" @default.
- W2054398465 modified "2023-10-09" @default.
- W2054398465 title "The Behavior of Thiochromanone and Isothiochromanone Sulfoxides in the Schmidt Reaction: Isolation of a Novel Azide Product from Thiochromone Sulfone" @default.
- W2054398465 doi "https://doi.org/10.1139/v75-038" @default.
- W2054398465 hasPublicationYear "1975" @default.
- W2054398465 type Work @default.
- W2054398465 sameAs 2054398465 @default.
- W2054398465 citedByCount "10" @default.
- W2054398465 countsByYear W20543984652012 @default.
- W2054398465 countsByYear W20543984652013 @default.
- W2054398465 crossrefType "journal-article" @default.
- W2054398465 hasAuthorship W2054398465A5040910872 @default.
- W2054398465 hasAuthorship W2054398465A5076158897 @default.
- W2054398465 hasAuthorship W2054398465A5088363184 @default.
- W2054398465 hasConcept C155647269 @default.
- W2054398465 hasConcept C178790620 @default.
- W2054398465 hasConcept C185592680 @default.
- W2054398465 hasConcept C2776131168 @default.
- W2054398465 hasConcept C2778448320 @default.
- W2054398465 hasConcept C2778806918 @default.
- W2054398465 hasConcept C2779625459 @default.
- W2054398465 hasConcept C2780263894 @default.
- W2054398465 hasConcept C2780997848 @default.
- W2054398465 hasConcept C2781076698 @default.
- W2054398465 hasConceptScore W2054398465C155647269 @default.
- W2054398465 hasConceptScore W2054398465C178790620 @default.
- W2054398465 hasConceptScore W2054398465C185592680 @default.
- W2054398465 hasConceptScore W2054398465C2776131168 @default.
- W2054398465 hasConceptScore W2054398465C2778448320 @default.
- W2054398465 hasConceptScore W2054398465C2778806918 @default.
- W2054398465 hasConceptScore W2054398465C2779625459 @default.
- W2054398465 hasConceptScore W2054398465C2780263894 @default.
- W2054398465 hasConceptScore W2054398465C2780997848 @default.
- W2054398465 hasConceptScore W2054398465C2781076698 @default.
- W2054398465 hasIssue "2" @default.
- W2054398465 hasLocation W20543984651 @default.
- W2054398465 hasOpenAccess W2054398465 @default.
- W2054398465 hasPrimaryLocation W20543984651 @default.
- W2054398465 hasRelatedWork W1938936214 @default.
- W2054398465 hasRelatedWork W1977343486 @default.
- W2054398465 hasRelatedWork W2009330412 @default.
- W2054398465 hasRelatedWork W2036045518 @default.
- W2054398465 hasRelatedWork W2043785867 @default.
- W2054398465 hasRelatedWork W2072163237 @default.
- W2054398465 hasRelatedWork W2077588681 @default.
- W2054398465 hasRelatedWork W2095351437 @default.
- W2054398465 hasRelatedWork W2127385036 @default.
- W2054398465 hasRelatedWork W3200181936 @default.
- W2054398465 hasVolume "53" @default.
- W2054398465 isParatext "false" @default.
- W2054398465 isRetracted "false" @default.
- W2054398465 magId "2054398465" @default.
- W2054398465 workType "article" @default.