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- W2054402008 abstract "The stage disorder of random mixture-GICS (RMGICS), stage 2 CocM1-cCl2-GICS (M=Mn,Ni), has been studied by means of (00L) X-ray diffraction. The (00L) X-ray diffraction pattern shows the prominent feature that the stage-disorder induced peak shift and full-width at half-maximum of the Bragg reflections oscillate as a function of the Bragg index of stage 2. The authors present a model calculation of the (00L) X-ray scattering intensity for systems with a stage disorder, which shows that the fractional probability of each stage is uniquely determined from the Bragg index dependence of the stage-disorder induced peak shift and full-width at half-maximum. The fractional probability of these compounds is determined by this method, and is discussed in terms of the scaling law relating the stage disorder to domain size (island size), charge transfer and temperature. The interlayer repulsion energy of these compounds which is the key for the stage order is shown to have the form of ui= upsilon 0i- alpha with alpha approximately=1 and 1.8*10-3 eV< upsilon 0<1.8*10-2 eV." @default.
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- W2054402008 date "1991-11-11" @default.
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- W2054402008 title "Stage disorder of random-mixture graphite intercalation compounds" @default.
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- W2054402008 doi "https://doi.org/10.1088/0953-8984/3/45/006" @default.
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