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• W2054406795 abstract "A technique has been developed for the determination of the exchangeable cation population of calcareous sandy material with cation exchange capacities of less than 1 meq/100 g. The technique involves the addition of exchange salt in the dry state to samples of porous media using original pore water as the exchange salt solvent. In applying this technique to samples from below the water table, the amount of pore water available for reaction is reduced by centrifuging in the field to bring the moisture content close to field capacity values. By utilizing the minimum amount of pore water, interferences during the exchange process due to calcite precipitation or dissolution are minimized. The extent of calcite dissolution or precipitation that occurs can be appraised by measuring alkalinity or total carbon on the pore water before and after addition of the exchange salt. Three salts, NH4C1, CsCl and LiCl were tested for their suitability for this technique. CsCl was found to be preferable because of its low tendency to dissolve carbonate and the preference of Cs+ on exchange sites. Application of the method to a field site in southern Ontario yielded a value of 0.51 ± 0·09 meq/100 g over 15 samples for the cation exchange capacity of a near surface glaciofluvial sand deposit. It is believed that this technique could be applied with reasonable accuracy and reproducibility to materials with exchange capacities of as low as 0·1 meq/100 g." @default.
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• W2054406795 date "1983-07-01" @default.
• W2054406795 modified "2023-09-30" @default.
• W2054406795 title "Field Determination of Cation Exchange Properties for Calcareous Sand" @default.
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• W2054406795 doi "https://doi.org/10.1111/j.1745-6584.1983.tb00743.x" @default.
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