Matches in SemOpenAlex for { <https://semopenalex.org/work/W2054407224> ?p ?o ?g. }
- W2054407224 endingPage "19866" @default.
- W2054407224 startingPage "19859" @default.
- W2054407224 abstract "We use Glauber dynamics Monte Carlo simulations and umbrella sampling techniques of a lattice gas model for confined water to validate the continuum estimates for the scaling of the activation barrier for evaporation with intersurface separation and barrier dependence on surface composition. Although thermal fluctuations significantly reduce the absolute values of activation barriers, ΔG*, we find a scaling exponent (ν = 1.9 ± 0.1) that agrees within statistical limits with the saddle-point approximation, ΔG* ∝ D2. Devising a method to measure a microscopic analogue of the contact angle θ from simulations, we find good agreement with the continuum prediction, ΔG* ∝ 1/cos θ. Combining the known result for the magnitude of the activation barrier and the evaporation rate of molecular water in a specified molecular confinement (Leung, K.; Luzar, A.; Bratko, D. Phys. Rev. Lett. 2003, 90, 065502-1) with the present scaling results allows us to predict the kinetic viability of the expulsion of water over a range of length scales and between arbitrary physically and chemically modified hydrophobic surfaces characterized by contact angles above 90°." @default.
- W2054407224 created "2016-06-24" @default.
- W2054407224 creator A5065022410 @default.
- W2054407224 date "2004-10-22" @default.
- W2054407224 modified "2023-09-26" @default.
- W2054407224 title "Activation Barrier Scaling for the Spontaneous Evaporation of Confined Water" @default.
- W2054407224 cites W1600692223 @default.
- W2054407224 cites W1966609152 @default.
- W2054407224 cites W1969814430 @default.
- W2054407224 cites W1970100900 @default.
- W2054407224 cites W1971183459 @default.
- W2054407224 cites W1975140804 @default.
- W2054407224 cites W1976326563 @default.
- W2054407224 cites W1976565467 @default.
- W2054407224 cites W1979430503 @default.
- W2054407224 cites W1981451240 @default.
- W2054407224 cites W1983272724 @default.
- W2054407224 cites W1986252462 @default.
- W2054407224 cites W1986938998 @default.
- W2054407224 cites W1988568995 @default.
- W2054407224 cites W1989165079 @default.
- W2054407224 cites W1990491270 @default.
- W2054407224 cites W1993214026 @default.
- W2054407224 cites W1994444219 @default.
- W2054407224 cites W1995900340 @default.
- W2054407224 cites W2000733905 @default.
- W2054407224 cites W2002813835 @default.
- W2054407224 cites W2006095154 @default.
- W2054407224 cites W2007175696 @default.
- W2054407224 cites W2012663156 @default.
- W2054407224 cites W2018688186 @default.
- W2054407224 cites W2019005630 @default.
- W2054407224 cites W2019075141 @default.
- W2054407224 cites W2022231452 @default.
- W2054407224 cites W2023750054 @default.
- W2054407224 cites W2028222924 @default.
- W2054407224 cites W2031272029 @default.
- W2054407224 cites W2034605484 @default.
- W2054407224 cites W2040004688 @default.
- W2054407224 cites W2044096024 @default.
- W2054407224 cites W2046175116 @default.
- W2054407224 cites W2046710114 @default.
- W2054407224 cites W2046802317 @default.
- W2054407224 cites W2050766227 @default.
- W2054407224 cites W2056760934 @default.
- W2054407224 cites W2058069146 @default.
- W2054407224 cites W2059865583 @default.
- W2054407224 cites W2069885783 @default.
- W2054407224 cites W2071280566 @default.
- W2054407224 cites W2073223560 @default.
- W2054407224 cites W2073948895 @default.
- W2054407224 cites W2080088959 @default.
- W2054407224 cites W2086426011 @default.
- W2054407224 cites W2086546357 @default.
- W2054407224 cites W2094473891 @default.
- W2054407224 cites W2095921114 @default.
- W2054407224 cites W2104129019 @default.
- W2054407224 cites W2106695780 @default.
- W2054407224 cites W2116425413 @default.
- W2054407224 cites W2131754023 @default.
- W2054407224 cites W2133445717 @default.
- W2054407224 cites W2137037787 @default.
- W2054407224 cites W2140216699 @default.
- W2054407224 cites W2158801277 @default.
- W2054407224 cites W2171753421 @default.
- W2054407224 cites W3102934655 @default.
- W2054407224 cites W4250362815 @default.
- W2054407224 cites W4256655203 @default.
- W2054407224 cites W5830164 @default.
- W2054407224 doi "https://doi.org/10.1021/jp0470703" @default.
- W2054407224 hasPublicationYear "2004" @default.
- W2054407224 type Work @default.
- W2054407224 sameAs 2054407224 @default.
- W2054407224 citedByCount "72" @default.
- W2054407224 countsByYear W20544072242012 @default.
- W2054407224 countsByYear W20544072242013 @default.
- W2054407224 countsByYear W20544072242014 @default.
- W2054407224 countsByYear W20544072242015 @default.
- W2054407224 countsByYear W20544072242016 @default.
- W2054407224 countsByYear W20544072242017 @default.
- W2054407224 countsByYear W20544072242018 @default.
- W2054407224 countsByYear W20544072242019 @default.
- W2054407224 countsByYear W20544072242020 @default.
- W2054407224 countsByYear W20544072242021 @default.
- W2054407224 countsByYear W20544072242022 @default.
- W2054407224 countsByYear W20544072242023 @default.
- W2054407224 crossrefType "journal-article" @default.
- W2054407224 hasAuthorship W2054407224A5065022410 @default.
- W2054407224 hasConcept C105795698 @default.
- W2054407224 hasConcept C120665830 @default.
- W2054407224 hasConcept C121332964 @default.
- W2054407224 hasConcept C121864883 @default.
- W2054407224 hasConcept C138885662 @default.
- W2054407224 hasConcept C147597530 @default.
- W2054407224 hasConcept C159467904 @default.
- W2054407224 hasConcept C185592680 @default.
- W2054407224 hasConcept C191486275 @default.
- W2054407224 hasConcept C19499675 @default.