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- W2054572009 abstract "Abstract The actinide concept proposed by Seaborg in 1945 involves a close relationship between the trivalent 4f (Ln) and the 5f (An) elements. The trivalent ions of these two families have very similar properties due to strong ionic bonding and similar ionic radii. Their similarity led to the successful formation of element 95–103 over the next 30 years by accurate prediction of the chemistry of the undiscovered elements. In the early 1950s, a small degree of covalency was proposed in the bonding of the lanthanide elements. However, controversy continues today on the degree of covalency in the bonds of the 4f and 5f elements. The interpretation of data in terms of covalency in the M–L bonds is reviewed with emphasis on which orbitals are involved." @default.
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- W2054572009 date "2002-10-01" @default.
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- W2054572009 title "Covalency in f-element bonds" @default.
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- W2054572009 doi "https://doi.org/10.1016/s0925-8388(02)00305-5" @default.
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