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• W2054592516 abstract "Abstract RE 3– x Mg x (Ni 0.7 Co 0.2 Mn 0.1 ) 9 ( x =0.5–1.25) alloys were prepared by induction melting and the influence of the partial substitution of RE (where RE stands for La-rich mischmetal) by Mg on the hydrogen storage and electrochemical properties of the alloys were investigated systematically. These alloys mainly consisted of three phases, La(Ni,Mn,Co) 5 phase, La 2 Ni 7 phase and Mg 2 Ni phase. The P-C-T isotherms showed that with Mg content increasing in the alloys, the hydrogen storage capacity first increased and reached the maximum capacity of 1.36 wt.% when x =1.0, and then decreased with x increasing further. Electrochemical studies revealed that the discharge capacity reached the maximum value of 380 mAh/g and the alloy electrode presented better cyclic stability when RE/Mg=2. The high rate discharge ability of the alloy electrodes was also improved by the substitution of Mg for RE. The RE 2 Mg(Ni 0.7 Co 0.2 Mn 0.1 ) 9 alloy exhibited better hydrogen absorption kinetics ( x =1.0)." @default.
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• W2054592516 date "2012-12-01" @default.
• W2054592516 modified "2023-09-27" @default.
• W2054592516 title "Influence of magnesium on electrochemical properties of RE3–xMgx(Ni0.7Co0.2Mn0.1)9 (x=0.5–1.25) alloy electrodes" @default.
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• W2054592516 doi "https://doi.org/10.1016/s1002-0721(12)60216-6" @default.
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