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- W2054602905 abstract "The rate of DMF exchange on [Tm (DMF)8]3+ has been determined by 1H- and 13C-NMR. linebroadening techniques. 1H-NMR. yields the following solvent exchange parameters; ΔH* = 33.2 (±0.5) kJ mol−1, ΔS* = 9.9 (±2.4) J K−1 mol−1and k (200 K) = 2.94 (±0.09)× 104 s−1, whilst results from 13C-NMR. are similar. No evidence, by 35C1-NMR., was found of contact ion-pair formation when the perchlorate salts were used." @default.
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- W2054602905 date "1982-03-17" @default.
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- W2054602905 title "Variable temperature multinuclear NMR. Investigation of dimethylformamide exchange on the octakis (N,N-dimethylformamide)-thulium(III) ion" @default.
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- W2054602905 doi "https://doi.org/10.1002/hlca.19820650216" @default.
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