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- W2054667536 abstract "In the present study, the sorption behavior of cesium was investigated in Ain Oussera soil around the Es-Salam reactor facility. This study was conducted using batch method under different physicochemical conditions including contact time, ionic strength, pH, solid/liquid ratio and temperature. The results showed that sorption followed pseudo-second-order kinetics with a good regression coefficients (R2 = 0.999). The activation energies were 11.26 and 15.21 kJ mol−1 which correspond to ion-exchange-type sorption mechanism. The adsorption was favored at low temperature and it was exothermic (ΔH0 < 0, with average value of −1.97 kJ mol−1) and spontaneous (ΔG0 < 0, with average value of −11.97 kJ mol−1 at 23 °C and −13.2 kJ mol−1 at 60 °C). The presence of competing cations such as K+ and Ca2+ ions in groundwater can significantly reduce the Cs adsorption onto soil. Desorption reaction was also investigated using three reagents with different ionic strengths (deionized water, groundwater and 0.1 M KCl solution). The results showed that Cs ions were preferentially distributed onto high affinity sorption sites." @default.
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- W2054667536 date "2010-12-01" @default.
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- W2054667536 title "Sorption behavior of cesium on Ain Oussera soil under different physicochemical conditions" @default.
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- W2054667536 doi "https://doi.org/10.1016/j.jhazmat.2010.08.084" @default.
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