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- W2054669904 abstract "Abstract E ⇄ Z photoisomerization reactions of stilbenes la‐c were studied in liquid‐crystalline (LC) phases and in the corresponding isotropic melts. Whereas viscosity has a moderate influence on the photostationary states, a strong effect caused by the regular incorporation of the stilbene molecules in the LC phases was observed. The direction of the isomerization can be reversed, up to the case of a one‐way isomerization Z → E for the tailored guest‐host system 1b/BS. Such an LC‐matrix effect is of typical highly ordered (smectic) phases with free volumina which are strictly limited by hydrophobic interactions; it could not be detected in a much more mobile nematic phase. Textures based on the birefringence of doped LC phases, differential‐scanning‐calorimetry (DSC) measurements and phase‐dependent absorption spectra were used for the interpretation." @default.
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- W2054669904 date "1995-01-01" @default.
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- W2054669904 title "Selectivity in the direction of photoisomerization reactions in liquid-crystalline guest-host systems" @default.
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- W2054669904 doi "https://doi.org/10.1002/recl.19951141107" @default.
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