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• W2054683675 abstract "Over the past two decades the photochemical and photophysical properties of Cu(I)–phenanthrolines ([Cu(NN)2]+) have been investigated in detail. A high degree of control of the metal-to-ligand charge-transfer (MLCT) absorption and luminescence properties of [Cu(NN)2]+ is now possible, by means of a thorough choice and positioning of the phenanthroline ligand substituents. Exchange of Cu(I) with a variety of metal ions (Mn+) allows tuning of the electrochemical and photophysical properties of the [M(NN)2]n+ motif. This has prompted the design of fascinating multicomponent molecular architectures (catenates, knots, rotaxanes, dendrimers) in which photoinduced intercomponent processes like energy- and electron-transfer occur. The possibility of a fine tuning of the absorption and emission properties, long excited state lifetimes, and a characteristic structural flexibility, suggest Cu(I)–phenathrolines as interesting alternatives to Ru(II)–polypyridines, still the most popular family of complexes among inorganic photochemists." @default.
• W2054683675 created "2016-06-24" @default.
• W2054683675 creator A5021250255 @default.
• W2054683675 date "2001-01-01" @default.
• W2054683675 modified "2023-10-16" @default.
• W2054683675 title "Photoactive mono- and polynuclear Cu(i)–phenanthrolines. A viable alternative to Ru(ii)–polypyridines?" @default.
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• W2054683675 doi "https://doi.org/10.1039/b000703j" @default.
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