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• W2054740097 abstract "The magnetic properties of the layered Ban+1ConO3n−1Br (n = 5 and 6) oxybromides have been determined by means of magnetization measurements and neutron diffraction under variable magnetic field. For n = 6, the magnetic phase diagram has been built on the basis of several features, including the notions of short-range ordering, spin reorientation, and spin-flop transitions. In those compounds, the competition between magnetic exchanges arise from the existence of [Ba2O2Br]− double-layers that separate perovskite 2D-blocks. The latter are dominated by ferromagnetic (FM) intraexchanges while the interblock exchanges are antiferromagnetic (AFM). Interestingly, a perturbation created by an external magnetic field could be on the same order of magnitude than the interblock exchange leading to a complex set of spin reorientations versus H and T. From the point of view of magneto-crystalline anisotropy, the AFM system with moments parallel to the c-axis turns into a FM system with moments aligned in the perpendicular (a,b) planes. The magnetic entropy is distributed within at least three phenomena, spread out in a wide range of temperature.Here, the influence of the magneto-crystalline anisotropy on the magnetocaloric effect is unambiguously shown." @default.
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• W2054740097 date "2010-05-28" @default.
• W2054740097 modified "2023-09-23" @default.
• W2054740097 title "Spin-Flop Transition and Magnetocaloric Effect through Disconnected Magnetic Blocks in Co^III/Co^IV Oxybromides" @default.
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• W2054740097 doi "https://doi.org/10.1021/cm100571v" @default.
• W2054740097 hasPublicationYear "2010" @default.
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