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• W2054791963 abstract "The Raman spectra of gaseous and solid nitrosyl chloride, ONCl, have been recorded from 10 to 2200 cm−1. In the spectrum of the gas, the three fundamentals for the isotopic species ON35Cl were observed at: ν1 = 1799.7, ν2 = 595.7, and ν3 = 331.8 cm−1. Large shifts from these frequencies were observed for the solid material. The infrared spectra of the gaseous and solid nitrosyl chloride were recorded from 30 to 2000 cm−1. The spectrum of the gas was recorded at a resolution of 0.06 cm−1 and the vibrational-rotational structure for both ν2 and ν3 was analyzed in the ground and excited vibrational states. Band origins were determined to be at 595.860(3) and 331.973(4) cm−1 for ν2 and ν3, respectively, for ON35Cl and the corresponding band centers for ON37Cl were approximately 594.9 and 328.2 cm−1. The pure rotational infrared spectrum of ONCl was recorded (20 to 120 cm−1) and interpreted in terms of a slightly asymmetric prolate top with centrifugal distortion. Series of 17 and 10 sharp Q branches were observed for the ON35Cl ground state and v3 = 1 excited state, respectively. A new force field based on new and existing data is proposed and discussed." @default.
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• W2054791963 date "1986-05-01" @default.
• W2054791963 modified "2023-09-27" @default.
• W2054791963 title "Raman and infrared spectra of gaseous and solid nitrosyl chloride" @default.
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• W2054791963 doi "https://doi.org/10.1016/0022-2852(86)90093-7" @default.
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