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• W2054796317 abstract "Abstract This is the first paper of a series of reports concerning extended‐chain crystals of flexible, linear high polymers. The general conditions for crystal growth are discussed. Polymer crystallization is described as a two‐step process: nucleation of each crystallizing molecule to a folded‐chain conformation, followed by an increase in fold length in a solid‐state reorganization step. This reorganization step is enhanced in the case of polyethylene by crystallization at high temperature under elevated pressure. Mechanical deformation during crystallization is also able to produce extended‐chain crystals. The most promising method, however, is crystallization during polymerization. Previous work on crystallization of polyethylene under elevated pressure is critically reviewed." @default.
• W2054796317 created "2016-06-24" @default.
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• W2054796317 date "1969-12-01" @default.
• W2054796317 modified "2023-10-18" @default.
• W2054796317 title "Extended-chain crystals. I. General crystallization conditions and review of pressure crystallization of polyethylene" @default.
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• W2054796317 doi "https://doi.org/10.1002/pol.1969.160071206" @default.
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