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- W2054796817 abstract "The conjugated carboxy-functionalized terpyridyl bimetal ruthenium complex [(tdctpy)Ru(dctpy-(ph)4-dctpy)Ru(tdctpy)][PF6]4 and [2]rotaxane by self-assembly of [(tdctpy)Ru(dctpy-(ph)4-dctpy)Ru(tdctpy)][PF6]4 with β-cyclodextrin are reported as sensitizer for dye-sensitized solar cells (DSSCs), where tdctpy = 4′-p-tolyl-4,4″-dicarboxy-2,2′ : 6,2″-terpyridine, dctpy = 4,4″-dicarboxy-2,2′ : 6,2″-terpyridine and dctpy-(ph)4-dctpy represents a bridging ligand where two 4,4″-dicarboxy-2,2′ : 6′,2″-terpyridine units are connected through four phenyl spacers in the 4′-position. The DSSCs fabricated utilizing these materials give typical electric power conversion efficiency of 0.013–0.523% under air mass (AM) 1.5, 100 mW cm−2 irradiation at room temperature. The terpyridyl bimetal ruthenium complex [(tdctpy)Ru(dctpy-(ph)4-dctpy)Ru(tdctpy)][PF6]4 with conjugated-bridge chains displayed much higher conversion efficiency compared with the carboxy-functionalized terpyridyl monometal ruthenium complex [tdctpy-Ru-(idctpy)][PF6]2, where idctpy = 4′-p-iodophenyl-4,4″-dicarboxy-2,2′ : 6,2″-terpyridine. [2]Rotaxane displayed the highest electric power conversion efficiency of 0.523% when β-cyclodextrin was introduced into the conjugated terpyridyl bimetal ruthenium complex and formed [2]rotaxane." @default.
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- W2054796817 date "2011-09-07" @default.
- W2054796817 modified "2023-10-16" @default.
- W2054796817 title "Rotaxane based on terpyridyl bimetal ruthenium complexes and β-cyclodextrin as organic sensitizer for dye-sensitized solar cells" @default.
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- W2054796817 doi "https://doi.org/10.1080/00958972.2011.613115" @default.
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