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- W2054800886 abstract "A fast atom bombardment mass spectrometric study of the meso-substituent effect of Octaethylporphyrins (OEPX, X = NH2, CH3, H, CHO, Cl, CN, NO2) is reported. The intensity of the [M + H]+ ion peaks was estimated quantitatively using an external standard, which was observed to be correlated linearly with the basicity (pK3) of the OEPX. The pK3 value of the OEPXs was obtained by titration with perchloric acid and it was observed to be correlated linearly with Hammett's σp value, with a ρ value of 1.38." @default.
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- W2054800886 date "1991-04-01" @default.
- W2054800886 modified "2023-09-25" @default.
- W2054800886 title "Linear dependence of the intensity of the [M + H]+ ion peak in fast atom bombardment mass spectrometry on the basicity ofmeso-substituted octaethylporphyrins" @default.
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- W2054800886 doi "https://doi.org/10.1002/oms.1210260416" @default.
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