FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2054804561> ?p ?o ?g. }

• W2054804561 endingPage "A158" @default.
• W2054804561 startingPage "A158" @default.
• W2054804561 abstract "Single-ion conducting block copolymer electrolytes were prepared in which counter ions were tethered to the polymer backbone to achieve a lithium transference number of unity. Through tailored anionic synthesis, the influence of counter ion placement on conductivity was investigated. Incorporating the anions outside the ion-conducting [poly(ethylene oxide)-based] block, such as in poly(lauryl methacrylate)-block-poly(lithium methacrylate)-block-poly methacrylate], known as PLMA-b-PLiMA-b-POEM, and P(LMA-r-LiMA)-b-POEM, caused lithium ions to dissociate from the carboxylate counter ions upon microphase separation of the POEM and PLMA blocks, yielding conductivities of S/cm at 70°C. In contrast, incorporating anions into the conducting block, as in PLMA-b-P(LiMA-r-OEM), rendered the majority of lithium ions immobile, resulting in conductivities one to two orders of magnitude lower over the range of temperatures studied for equivalent stoichiometries. Converting the carboxylate anion to one that effectively delocalized charge through complexation with the Lewis acid raised the conductivity of the latter system to values comparable to those of the other electrolyte architectures. Ion dissociation could thus be equivalently achieved by using a low charge density counter ion or by spatially isolating the counter ion from the ion-conducting domains by microphase separation. © 2004 The Electrochemical Society. All rights reserved." @default.
• W2054804561 created "2016-06-24" @default.
• W2054804561 creator A5020269897 @default.
• W2054804561 creator A5051069092 @default.
• W2054804561 creator A5051375203 @default.
• W2054804561 creator A5069822265 @default.
• W2054804561 creator A5075466401 @default.
• W2054804561 creator A5091841604 @default.
• W2054804561 date "2005-01-01" @default.
• W2054804561 modified "2023-10-18" @default.
• W2054804561 title "Effect of Counter Ion Placement on Conductivity in Single-Ion Conducting Block Copolymer Electrolytes" @default.
• W2054804561 cites W106134948 @default.
• W2054804561 cites W1972554557 @default.
• W2054804561 cites W1973608660 @default.
• W2054804561 cites W1974497705 @default.
• W2054804561 cites W1975127905 @default.
• W2054804561 cites W1982755389 @default.
• W2054804561 cites W1982979288 @default.
• W2054804561 cites W1986216992 @default.
• W2054804561 cites W1990991492 @default.
• W2054804561 cites W1991997169 @default.
• W2054804561 cites W1993971435 @default.
• W2054804561 cites W1994850210 @default.
• W2054804561 cites W1998745879 @default.
• W2054804561 cites W2002190827 @default.
• W2054804561 cites W2015745064 @default.
• W2054804561 cites W2021588338 @default.
• W2054804561 cites W2032953510 @default.
• W2054804561 cites W2034943954 @default.
• W2054804561 cites W2042140504 @default.
• W2054804561 cites W2058284592 @default.
• W2054804561 cites W2061955337 @default.
• W2054804561 cites W2067996940 @default.
• W2054804561 cites W2070348564 @default.
• W2054804561 cites W2073368973 @default.
• W2054804561 cites W2080225788 @default.
• W2054804561 cites W2087236620 @default.
• W2054804561 cites W2089403233 @default.
• W2054804561 cites W2092931307 @default.
• W2054804561 cites W2116018614 @default.
• W2054804561 cites W2130748069 @default.
• W2054804561 cites W2148927942 @default.
• W2054804561 cites W2155934257 @default.
• W2054804561 cites W2158197941 @default.
• W2054804561 doi "https://doi.org/10.1149/1.1828244" @default.
• W2054804561 hasPublicationYear "2005" @default.
• W2054804561 type Work @default.
• W2054804561 sameAs 2054804561 @default.
• W2054804561 citedByCount "136" @default.
• W2054804561 countsByYear W20548045612012 @default.
• W2054804561 countsByYear W20548045612013 @default.
• W2054804561 countsByYear W20548045612014 @default.
• W2054804561 countsByYear W20548045612015 @default.
• W2054804561 countsByYear W20548045612016 @default.
• W2054804561 countsByYear W20548045612017 @default.
• W2054804561 countsByYear W20548045612018 @default.
• W2054804561 countsByYear W20548045612019 @default.
• W2054804561 countsByYear W20548045612020 @default.
• W2054804561 countsByYear W20548045612021 @default.
• W2054804561 countsByYear W20548045612022 @default.
• W2054804561 countsByYear W20548045612023 @default.
• W2054804561 crossrefType "journal-article" @default.
• W2054804561 hasAuthorship W2054804561A5020269897 @default.
• W2054804561 hasAuthorship W2054804561A5051069092 @default.
• W2054804561 hasAuthorship W2054804561A5051375203 @default.
• W2054804561 hasAuthorship W2054804561A5069822265 @default.
• W2054804561 hasAuthorship W2054804561A5075466401 @default.
• W2054804561 hasAuthorship W2054804561A5091841604 @default.
• W2054804561 hasConcept C102931765 @default.
• W2054804561 hasConcept C131540310 @default.
• W2054804561 hasConcept C132050475 @default.
• W2054804561 hasConcept C134018914 @default.
• W2054804561 hasConcept C138679309 @default.
• W2054804561 hasConcept C145148216 @default.
• W2054804561 hasConcept C147789679 @default.
• W2054804561 hasConcept C15920480 @default.
• W2054804561 hasConcept C161790260 @default.
• W2054804561 hasConcept C17525397 @default.
• W2054804561 hasConcept C178790620 @default.
• W2054804561 hasConcept C179104552 @default.
• W2054804561 hasConcept C185592680 @default.
• W2054804561 hasConcept C188027245 @default.
• W2054804561 hasConcept C192562407 @default.
• W2054804561 hasConcept C21774173 @default.
• W2054804561 hasConcept C2777801237 @default.
• W2054804561 hasConcept C2778541603 @default.
• W2054804561 hasConcept C2779851234 @default.
• W2054804561 hasConcept C34814092 @default.
• W2054804561 hasConcept C521977710 @default.
• W2054804561 hasConcept C68801617 @default.
• W2054804561 hasConcept C70050531 @default.
• W2054804561 hasConcept C71924100 @default.
• W2054804561 hasConceptScore W2054804561C102931765 @default.
• W2054804561 hasConceptScore W2054804561C131540310 @default.
• W2054804561 hasConceptScore W2054804561C132050475 @default.
• W2054804561 hasConceptScore W2054804561C134018914 @default.
• W2054804561 hasConceptScore W2054804561C138679309 @default.
• W2054804561 hasConceptScore W2054804561C145148216 @default.

• next