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• W2054859727 abstract "[reaction: see text]. The beta-fragmentation of 2,2-difluoro-saccharide anomeric alkoxyl radicals, generated under oxidative condition by treatment of the respective alcohols with (diacetoxyiodo)benzene (DIB) and iodine, afforded 1,1-difluoro-1-iodo alditols in high yield. The reactivity of the fluorinated radical generated by rupture of the C-I bond has been preliminarily assessed by reductive deiodination with tributyltin hydride/AIBN and intermolecular allylation using the Keck reaction." @default.
• W2054859727 created "2016-06-24" @default.
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• W2054859727 date "2003-10-01" @default.
• W2054859727 modified "2023-10-16" @default.
• W2054859727 title "Fragmentation of Carbohydrate Anomeric Alkoxyl Radicals: A New Synthesis of 1,1-Difluoro-1-iodo Alditols" @default.
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• W2054859727 doi "https://doi.org/10.1021/ol035611l" @default.
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