Matches in SemOpenAlex for { <https://semopenalex.org/work/W2054872257> ?p ?o ?g. }
- W2054872257 endingPage "1960" @default.
- W2054872257 startingPage "1960" @default.
- W2054872257 abstract "Redox potential inversion was observed during the two-electron (2e−) reduction of two novel heterometal trinuclear complexes, [Co2Mo(η5-C5Me5)2(S2C6H4)2(CO)2] (1) and [Rh2Mo(η5-C5Me5)2(S2C6H4)2(CO)2] (2), the metalladithiolenes of which were found to communicate electronically via a Mo(CO)2 moiety through two Co/Rh–Mo bonds. The redox properties and structural changes associated with each complex were investigated. 1 showed both two-step one-electron (1e−) reductions with a normal-order redox potential difference and a one-step 2e−reduction with a redox potential inversion that depended on the solvent and electrolyte. The size of the counter cation was found to significantly influence the reduction behaviour of 1. In contrast, 2 showed only a one-step 2e−reduction that didn't depend on the solvent–electrolyte conditions. The CO coordination mode in each reduction underwent a reversible structural reorganization upon reduction, from a semibridging configuration between the Co/Rh atoms and the Mo atom in the neutral form to a bridging configuration in the reduced form. The local coordination structure of the metal atoms in the dianion 22−2− was experimentally determined for the first time. The interactions between Co and CO in 1 were weaker than the interactions between Rh and CO in 2, and differences in the interaction strengths, together with the influence of the solvent–electrolyte medium, were found to determine the redox processes available to the complexes." @default.
- W2054872257 created "2016-06-24" @default.
- W2054872257 creator A5006943303 @default.
- W2054872257 creator A5024171030 @default.
- W2054872257 creator A5033421801 @default.
- W2054872257 creator A5048183759 @default.
- W2054872257 creator A5068421230 @default.
- W2054872257 creator A5070692378 @default.
- W2054872257 creator A5089786787 @default.
- W2054872257 date "2011-01-01" @default.
- W2054872257 modified "2023-10-02" @default.
- W2054872257 title "Normal and inverted redox potentials and structural changes tuned by medium effects in [M2Mo(η5-C5Me5)2(S2C6H4)2(CO)2] (M: Co, Rh)" @default.
- W2054872257 cites W1457429939 @default.
- W2054872257 cites W1564047174 @default.
- W2054872257 cites W1602932472 @default.
- W2054872257 cites W1691067281 @default.
- W2054872257 cites W1964787731 @default.
- W2054872257 cites W1968355139 @default.
- W2054872257 cites W1971731306 @default.
- W2054872257 cites W1972295548 @default.
- W2054872257 cites W1976858533 @default.
- W2054872257 cites W1980035913 @default.
- W2054872257 cites W1980216394 @default.
- W2054872257 cites W1980304241 @default.
- W2054872257 cites W1981374580 @default.
- W2054872257 cites W1985909627 @default.
- W2054872257 cites W1986432804 @default.
- W2054872257 cites W1991577629 @default.
- W2054872257 cites W1992942109 @default.
- W2054872257 cites W1997394068 @default.
- W2054872257 cites W2001338086 @default.
- W2054872257 cites W2005400331 @default.
- W2054872257 cites W2008770318 @default.
- W2054872257 cites W2011227483 @default.
- W2054872257 cites W2011413203 @default.
- W2054872257 cites W2011874257 @default.
- W2054872257 cites W2016350504 @default.
- W2054872257 cites W2016813535 @default.
- W2054872257 cites W2022835158 @default.
- W2054872257 cites W2026598559 @default.
- W2054872257 cites W2028792526 @default.
- W2054872257 cites W2030003306 @default.
- W2054872257 cites W2031904472 @default.
- W2054872257 cites W2035011106 @default.
- W2054872257 cites W2037336242 @default.
- W2054872257 cites W2040338073 @default.
- W2054872257 cites W2041627060 @default.
- W2054872257 cites W2044361851 @default.
- W2054872257 cites W2045603989 @default.
- W2054872257 cites W2046719000 @default.
- W2054872257 cites W2048110396 @default.
- W2054872257 cites W2050291848 @default.
- W2054872257 cites W2057353271 @default.
- W2054872257 cites W2060300161 @default.
- W2054872257 cites W2060757838 @default.
- W2054872257 cites W2061616260 @default.
- W2054872257 cites W2064235306 @default.
- W2054872257 cites W2065430897 @default.
- W2054872257 cites W2069881911 @default.
- W2054872257 cites W2074805429 @default.
- W2054872257 cites W2083619827 @default.
- W2054872257 cites W2085626852 @default.
- W2054872257 cites W2085724000 @default.
- W2054872257 cites W2088131713 @default.
- W2054872257 cites W2088167673 @default.
- W2054872257 cites W2088481620 @default.
- W2054872257 cites W2097043873 @default.
- W2054872257 cites W2105510993 @default.
- W2054872257 cites W2121243460 @default.
- W2054872257 cites W2131673030 @default.
- W2054872257 cites W2142240152 @default.
- W2054872257 cites W2152627285 @default.
- W2054872257 cites W2163063819 @default.
- W2054872257 cites W2167436279 @default.
- W2054872257 cites W2317669766 @default.
- W2054872257 cites W2322224545 @default.
- W2054872257 cites W2921020245 @default.
- W2054872257 cites W2949337600 @default.
- W2054872257 cites W2950071121 @default.
- W2054872257 cites W2950299723 @default.
- W2054872257 cites W2950846368 @default.
- W2054872257 cites W2951177149 @default.
- W2054872257 cites W2953012449 @default.
- W2054872257 cites W3081956156 @default.
- W2054872257 cites W4292053748 @default.
- W2054872257 doi "https://doi.org/10.1039/c1sc00272d" @default.
- W2054872257 hasPublicationYear "2011" @default.
- W2054872257 type Work @default.
- W2054872257 sameAs 2054872257 @default.
- W2054872257 citedByCount "18" @default.
- W2054872257 countsByYear W20548722572012 @default.
- W2054872257 countsByYear W20548722572013 @default.
- W2054872257 countsByYear W20548722572014 @default.
- W2054872257 countsByYear W20548722572015 @default.
- W2054872257 countsByYear W20548722572016 @default.
- W2054872257 countsByYear W20548722572017 @default.
- W2054872257 countsByYear W20548722572018 @default.
- W2054872257 countsByYear W20548722572019 @default.