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- W2054900036 abstract "The ion distribution around electrostatically stabilized polystyrene latex spheres for different ionic strengths is investigated by ellipsometric light scattering. This method is sensitive to the refractive index profile around colloidal particles, which is affected by the local salt content. At an average salt concentration of c* = 10(-4) mol L(-1), the ion concentration at the particle interface increases discontinuously, and a layer of high salt content with 20-30 nm thickness is built up. The observation cannot be explained within the framework of the Poisson-Boltzmann equation; it rather resembles a prewetting transition. Interactions that could possibly lead to a stabilization of the observed layer of high salt content are discussed." @default.
- W2054900036 created "2016-06-24" @default.
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- W2054900036 date "2006-11-23" @default.
- W2054900036 modified "2023-10-14" @default.
- W2054900036 title "Ion Distribution around Electrostatically Stabilized Polystyrene Latex Particles Studied by Ellipsometric Light Scattering" @default.
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- W2054900036 doi "https://doi.org/10.1021/la062033j" @default.
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