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- W2054900530 abstract "The structure of the compound trans-[PdCl {C(N-ϱ-C6H4OMe)C(Me)N-ϱ-C6H4OMe} (PPh3)2] was solved, using a conventional combination of Patterson and Fourier functions, least-squares refinements and electron density difference maps, to a reliability index R of 0.069 for the 2923 observed reflections collected by four-circle diffractometer. The palladium arom is surrounded in a roughly planar fashion by two trans phosphorus atoms, a chlorine atom, and a σ-bonded carbon atom of the diazabutadienyl group. This group assumes a trans configuration, the NCCN fragment being virtually planar and nearly normal to the mean coordination plane. The Pdligand bond lengths are: PdC 1.98(1), PdCl 2.41(1),PDP(1) 2.33(1) and PdP(2) 2.35(1) Å." @default.
- W2054900530 created "2016-06-24" @default.
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- W2054900530 date "1980-01-01" @default.
- W2054900530 modified "2023-09-27" @default.
- W2054900530 title "Structure of trans-chloro-1,4-bis(ϱ-methoxyphenyl)-1,4-diaza-3methylbutadiene-2-yl-bis(triphenylphosphine)-palladium(II)" @default.
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- W2054900530 doi "https://doi.org/10.1016/s0022-328x(00)83494-4" @default.
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