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- W2054919686 abstract "The reaction of [PtMeX(COD)] with 2-(diphenylphosphino)pyridine (Ph2Ppy) in 1 : 2 stoichiometry yields [PtMeX(Ph2Ppy)2] (X = Me, Ia; Cl, Ib; or I, Ic). Reaction of [PtMeCl(COD)] with one equivalent of Ph2Ppy gives the dinuclear complex [PtMeCl(Ph2Ppy)]2 (II). Several reactions of Ib have been studied. Treatment of Ib with NaY gives the cationic complexes [PtMe(η2-Ph2Ppy)(Ph2Ppy)][Y] (Y = BPh4, Id or BF4, Ie). The crystals of Id are triclinic, space group P1 with two molecules in a unit cell of dimensions a 10.006(6), b 14.240(8), c 18.368(6) Å, α 80.93(4), β 74.60(3), γ 89.23(5)°. The platinum atom has square planar geometry. The phosphorus atom of the chelated phosphine is trans to the methyl group" @default.
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- W2054919686 date "1990-06-01" @default.
- W2054919686 modified "2023-10-17" @default.
- W2054919686 title "Methylplatinum(II) complexes containing 2-(diphenylphosphino)pyridine (Ph2Ppy). Crystal and molecular structure of [PtMe(η2-Ph2Ppy)(Ph2Ppy)][BPh4]" @default.
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- W2054919686 doi "https://doi.org/10.1016/0022-328x(90)85436-3" @default.
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