Matches in SemOpenAlex for { <https://semopenalex.org/work/W2054932903> ?p ?o ?g. }
- W2054932903 endingPage "4126" @default.
- W2054932903 startingPage "4118" @default.
- W2054932903 abstract "End-functionalized, regioregular poly(3-hexylthiophene) (P3HT) was synthesized by a combination of a controlled polymerization technique and postpolymerization functionalization. Both ends of the polymer chains were terminated with fullerene units to create an internal electron accepting−donating−accepting molecule, methylfulleropyrrolidine−poly(3-hexylthiophene)−methylfulleropyrrolidine (C60-P3HT-C60). The molecular properties of the polymer were characterized using 1H NMR spectroscopy, size exclusion chromatography (SEC), ultraviolet−visible (UV−vis) absorption spectroscopy, and fluorescence spectroscopy. These results show that the fullerene units are covalently bound to the polymer chain ends. Differential scanning calorimetry (DSC), wide-angle X-ray scattering (WAXS), and small-angle X-ray scattering (SAXS) were used to determine the bulk microstructure of the polymers. In addition, atomic force microscopy (AFM) was used to examine spun-cast thin films. These experiments revealed that microphase separation occurs between the main polymer chain and the fullerene end groups and suggests the creation of two distinct semicrystalline regimes in C60-P3HT-C60 that are similar to those seen in a compositionally similar blend of P3HT and C60. This comparable domain formation, coupled with the possibility of enhanced charge transfer associated with an internal donor−acceptor material, makes C60-P3HT-C60 a promising candidate as a material in bulk heterojunction organic photovoltaics." @default.
- W2054932903 created "2016-06-24" @default.
- W2054932903 creator A5010598326 @default.
- W2054932903 creator A5011555432 @default.
- W2054932903 creator A5031829724 @default.
- W2054932903 creator A5044358227 @default.
- W2054932903 creator A5071975512 @default.
- W2054932903 date "2009-05-21" @default.
- W2054932903 modified "2023-10-09" @default.
- W2054932903 title "Synthesis, Optical Properties, and Microstructure of a Fullerene-Terminated Poly(3-hexylthiophene)" @default.
- W2054932903 cites W1974548162 @default.
- W2054932903 cites W1975313650 @default.
- W2054932903 cites W1979063792 @default.
- W2054932903 cites W1979162682 @default.
- W2054932903 cites W1982296561 @default.
- W2054932903 cites W1987849663 @default.
- W2054932903 cites W1996291528 @default.
- W2054932903 cites W1999711096 @default.
- W2054932903 cites W2001817712 @default.
- W2054932903 cites W2009078458 @default.
- W2054932903 cites W2015665309 @default.
- W2054932903 cites W2015728413 @default.
- W2054932903 cites W2017647960 @default.
- W2054932903 cites W2019440705 @default.
- W2054932903 cites W2020574524 @default.
- W2054932903 cites W2022584373 @default.
- W2054932903 cites W2024683615 @default.
- W2054932903 cites W2024839231 @default.
- W2054932903 cites W2025177295 @default.
- W2054932903 cites W2025583925 @default.
- W2054932903 cites W2028011934 @default.
- W2054932903 cites W2028249376 @default.
- W2054932903 cites W2029064627 @default.
- W2054932903 cites W2037345079 @default.
- W2054932903 cites W2039227348 @default.
- W2054932903 cites W2040563149 @default.
- W2054932903 cites W2041769139 @default.
- W2054932903 cites W2043320969 @default.
- W2054932903 cites W2046230993 @default.
- W2054932903 cites W2052276957 @default.
- W2054932903 cites W2052590748 @default.
- W2054932903 cites W2055617029 @default.
- W2054932903 cites W2056285691 @default.
- W2054932903 cites W2059554931 @default.
- W2054932903 cites W2065081603 @default.
- W2054932903 cites W2066318420 @default.
- W2054932903 cites W2073328540 @default.
- W2054932903 cites W2074289268 @default.
- W2054932903 cites W2075216142 @default.
- W2054932903 cites W2078734082 @default.
- W2054932903 cites W2079545197 @default.
- W2054932903 cites W2081097296 @default.
- W2054932903 cites W2081835379 @default.
- W2054932903 cites W2083013851 @default.
- W2054932903 cites W2083174643 @default.
- W2054932903 cites W2089574073 @default.
- W2054932903 cites W2094140969 @default.
- W2054932903 cites W2096174364 @default.
- W2054932903 cites W2100077118 @default.
- W2054932903 cites W2103717892 @default.
- W2054932903 cites W2108308620 @default.
- W2054932903 cites W2110138051 @default.
- W2054932903 cites W2113807895 @default.
- W2054932903 cites W2116372775 @default.
- W2054932903 cites W2122055965 @default.
- W2054932903 cites W2123711607 @default.
- W2054932903 cites W2125181865 @default.
- W2054932903 cites W2125616696 @default.
- W2054932903 cites W2132012759 @default.
- W2054932903 cites W2140453622 @default.
- W2054932903 cites W2142142859 @default.
- W2054932903 cites W2150677598 @default.
- W2054932903 cites W2150788377 @default.
- W2054932903 cites W2152036250 @default.
- W2054932903 cites W2172949807 @default.
- W2054932903 doi "https://doi.org/10.1021/ma900312a" @default.
- W2054932903 hasPublicationYear "2009" @default.
- W2054932903 type Work @default.
- W2054932903 sameAs 2054932903 @default.
- W2054932903 citedByCount "54" @default.
- W2054932903 countsByYear W20549329032012 @default.
- W2054932903 countsByYear W20549329032013 @default.
- W2054932903 countsByYear W20549329032014 @default.
- W2054932903 countsByYear W20549329032015 @default.
- W2054932903 countsByYear W20549329032016 @default.
- W2054932903 countsByYear W20549329032017 @default.
- W2054932903 countsByYear W20549329032018 @default.
- W2054932903 countsByYear W20549329032019 @default.
- W2054932903 countsByYear W20549329032020 @default.
- W2054932903 countsByYear W20549329032021 @default.
- W2054932903 countsByYear W20549329032022 @default.
- W2054932903 crossrefType "journal-article" @default.
- W2054932903 hasAuthorship W2054932903A5010598326 @default.
- W2054932903 hasAuthorship W2054932903A5011555432 @default.
- W2054932903 hasAuthorship W2054932903A5031829724 @default.
- W2054932903 hasAuthorship W2054932903A5044358227 @default.
- W2054932903 hasAuthorship W2054932903A5071975512 @default.
- W2054932903 hasConcept C120665830 @default.