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- W2054947710 abstract "The electron-phonon interaction in mixed-valence systems is modeled on the basis of an Anderson-like Hamiltonian that describes a cluster of one metallic rare-earth cation surrounded by six anions. Coupling between the electronic and phononic variables is introduced, keeping two different phonon modes: a breathing and an asymmetric mode. The first, related to the ionic radius, is treated exactly. The asymmetric mode, which determines the sd-f hybridization, is dealt with in the Born-Oppenheimer approximation. A variety of experimental results are adequately accounted for by this simple model, like the anomalous thermal expansion, the Debye-Waller factor, the phonon softening and broadening, and the charge-distance correlation." @default.
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- W2054947710 date "1991-02-01" @default.
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- W2054947710 title "Electron-phonon coupling in mixed-valence systems" @default.
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- W2054947710 doi "https://doi.org/10.1103/physrevb.43.3593" @default.
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