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- W2054954398 abstract "Abstract Synchrotron radiation-pump and laser-probe spectroscopy is employed to observe CN radicals in the vibronically ground state produced from CH 3 CN. The photon energy of synchrotron radiation is changed from 13.6 to 18.6 eV. The laser-induced fluorescence signal is measured as a function of the photon energy with the laser wavelength fixed at the CN( B 2 Σ + , v B =0← X 2 Σ + , v X =0) transition. The onset of 15.4 eV of the fluorescence signal indicates that the detected CN( X 2 Σ + ) radicals result from dissociative ionization of CH 3 CN. The partial cross section for the formation of CN( X 2 Σ + ) is estimated to be 0.1–0.5 Mb and is compared with that for the CH 3 + formation." @default.
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- W2054954398 date "2001-08-01" @default.
- W2054954398 modified "2023-09-27" @default.
- W2054954398 title "Laser-induced fluorescence spectroscopy of CN(X2Σ+) radicals produced by vacuum UV photoexcitation of CH3CN with synchrotron radiation" @default.
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- W2054954398 doi "https://doi.org/10.1016/s0368-2048(01)00288-2" @default.
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