Matches in SemOpenAlex for { <https://semopenalex.org/work/W2054958899> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2054958899 endingPage "274" @default.
- W2054958899 startingPage "264" @default.
- W2054958899 abstract "DFT calculations using the B3LYP functional support the suggestion that the [(terpy)(H(2)O)Mn(IV)(micro-O)(2)Mn(III)(H(2)O)(terpy)](3+) (terpy=2,2':6,2' '-terpyridine) complex functions as a synthetic O(2) catalyst. The calculated barrier for O-O bond formation with water is 23 kcal/mol. In this complex, as well as in models of the oxygen evolving complex in PSII, the active species is a Mn(IV)-oxyl radical. From comparisons with inactive Mn(V)-oxo complexes, it is proposed that radical formation is actually a requirement for O(2) formation activity in Mn-complexes." @default.
- W2054958899 created "2016-06-24" @default.
- W2054958899 creator A5008023056 @default.
- W2054958899 creator A5066524853 @default.
- W2054958899 creator A5068989141 @default.
- W2054958899 date "2003-11-25" @default.
- W2054958899 modified "2023-10-16" @default.
- W2054958899 title "Oxyl Radical Required for O−O Bond Formation in Synthetic Mn-Catalyst" @default.
- W2054958899 cites W1961714136 @default.
- W2054958899 cites W1977597058 @default.
- W2054958899 cites W1985581256 @default.
- W2054958899 cites W1989917955 @default.
- W2054958899 cites W2015420932 @default.
- W2054958899 cites W2024539997 @default.
- W2054958899 cites W2026673235 @default.
- W2054958899 cites W2032517458 @default.
- W2054958899 cites W2033033156 @default.
- W2054958899 cites W2038533471 @default.
- W2054958899 cites W2048451151 @default.
- W2054958899 cites W2049079467 @default.
- W2054958899 cites W2073637781 @default.
- W2054958899 cites W2105125469 @default.
- W2054958899 cites W2105643413 @default.
- W2054958899 doi "https://doi.org/10.1021/ic0348188" @default.
- W2054958899 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14704076" @default.
- W2054958899 hasPublicationYear "2003" @default.
- W2054958899 type Work @default.
- W2054958899 sameAs 2054958899 @default.
- W2054958899 citedByCount "116" @default.
- W2054958899 countsByYear W20549588992012 @default.
- W2054958899 countsByYear W20549588992013 @default.
- W2054958899 countsByYear W20549588992014 @default.
- W2054958899 countsByYear W20549588992015 @default.
- W2054958899 countsByYear W20549588992016 @default.
- W2054958899 countsByYear W20549588992017 @default.
- W2054958899 countsByYear W20549588992018 @default.
- W2054958899 countsByYear W20549588992019 @default.
- W2054958899 countsByYear W20549588992020 @default.
- W2054958899 countsByYear W20549588992021 @default.
- W2054958899 countsByYear W20549588992022 @default.
- W2054958899 crossrefType "journal-article" @default.
- W2054958899 hasAuthorship W2054958899A5008023056 @default.
- W2054958899 hasAuthorship W2054958899A5066524853 @default.
- W2054958899 hasAuthorship W2054958899A5068989141 @default.
- W2054958899 hasConcept C139066938 @default.
- W2054958899 hasConcept C155647269 @default.
- W2054958899 hasConcept C161790260 @default.
- W2054958899 hasConcept C178790620 @default.
- W2054958899 hasConcept C185592680 @default.
- W2054958899 hasConcept C2781350956 @default.
- W2054958899 hasConcept C528890316 @default.
- W2054958899 hasConcept C540031477 @default.
- W2054958899 hasConcept C544153396 @default.
- W2054958899 hasConcept C71240020 @default.
- W2054958899 hasConcept C8010536 @default.
- W2054958899 hasConceptScore W2054958899C139066938 @default.
- W2054958899 hasConceptScore W2054958899C155647269 @default.
- W2054958899 hasConceptScore W2054958899C161790260 @default.
- W2054958899 hasConceptScore W2054958899C178790620 @default.
- W2054958899 hasConceptScore W2054958899C185592680 @default.
- W2054958899 hasConceptScore W2054958899C2781350956 @default.
- W2054958899 hasConceptScore W2054958899C528890316 @default.
- W2054958899 hasConceptScore W2054958899C540031477 @default.
- W2054958899 hasConceptScore W2054958899C544153396 @default.
- W2054958899 hasConceptScore W2054958899C71240020 @default.
- W2054958899 hasConceptScore W2054958899C8010536 @default.
- W2054958899 hasIssue "1" @default.
- W2054958899 hasLocation W20549588991 @default.
- W2054958899 hasLocation W20549588992 @default.
- W2054958899 hasOpenAccess W2054958899 @default.
- W2054958899 hasPrimaryLocation W20549588991 @default.
- W2054958899 hasRelatedWork W2060480305 @default.
- W2054958899 hasRelatedWork W2082815683 @default.
- W2054958899 hasRelatedWork W2128778330 @default.
- W2054958899 hasRelatedWork W2253623815 @default.
- W2054958899 hasRelatedWork W2319274113 @default.
- W2054958899 hasRelatedWork W2406437931 @default.
- W2054958899 hasRelatedWork W4234641955 @default.
- W2054958899 hasRelatedWork W568177862 @default.
- W2054958899 hasRelatedWork W588542595 @default.
- W2054958899 hasRelatedWork W1877131787 @default.
- W2054958899 hasVolume "43" @default.
- W2054958899 isParatext "false" @default.
- W2054958899 isRetracted "false" @default.
- W2054958899 magId "2054958899" @default.
- W2054958899 workType "article" @default.