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• W2054982362 abstract "Abstract We have studied the interpolyelectrolyte complexation in chloroform between polystyrene- block -poly(cetyltrimethylammonium acrylate), (PA − CTA + ), and poly(2-(methacryloyloxy)ethyldimethylethyl-ammonium dodecyl sulfate) (quaternized poly(2-(dimethylamino)ethyl methacrylate) complexed with sodium dodecyl sulfate), (PDMAEMAQ + DS − ). Turbidimetry, dynamic/static light scattering, and transmission electron microscopy show the formation of large aggregated interpolyelectrolyte complex species, which are colloidally stable in chloroform or even chloroform-soluble if the certain conditions are met. We suggest such co-assemblies to be micellar species with a core assembled from electrostatically coupled fragments of the polymeric components. The corona is built up either from a mixture of polystyrene blocks and excessive fragments of (PDMAEMAQ + DS − ) chains or from a mixture of polystyrene blocks and excessive fragments of (PA − CTA + ) blocks, depending on which polymeric component was taken in excess for the interpolyelectrolyte complexation. However, their real structures may deviate from such idealized consideration because of the non-equilibrium character of interpolyelectrolyte complexation in organic media of low polarity." @default.
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• W2054982362 date "2011-09-01" @default.
• W2054982362 modified "2023-09-25" @default.
• W2054982362 title "Interpolyelectrolyte complexes of diblock copolymers via interaction of complementary polyelectrolyte–surfactant complexes in chloroform" @default.
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• W2054982362 doi "https://doi.org/10.1016/j.polymer.2011.07.017" @default.
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