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• W2054998410 abstract "A trianionic ligand H3L (2-hydroxy-N-(2-{[(2-hydroxyphenyl)methylene]amino}-2-methylpropyl)benzamide) with an inner N2O2 coordination site and an oxygen atom coming from an amide function not involved in this site yields monoanionic LCu− complexes that react with Ln(hfa)3·2H2O (hfa = hexafluoroacetylacetonato ligand) to give dinuclear Cu–Ln complexes that self-assemble into tetranuclear species, as demonstrated by the structural determination of the [LCuDy(hfa)2(dmf)2]2 complex. High-spin species are then isolated for two ferromagnetic interactions are active in the [Cu–Gd]2 entities, through the double phenoxo bridge (J = 3.2 cm−1) and through the single amide bridge (j = 0.54 cm−1). These interactions are still present in the [Cu–Tb]2 and [Cu–Dy]2 complexes which behave as single molecule magnets (SMMs), due to the introduction of anisotropic Ln ions in place of Gd ions." @default.
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• W2054998410 date "2008-01-01" @default.
• W2054998410 modified "2023-10-18" @default.
• W2054998410 title "Tetranuclear [Cu–Ln]2 single molecule magnets: synthesis, structural and magnetic studies" @default.
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• W2054998410 doi "https://doi.org/10.1039/b716098d" @default.
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