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- W2055000056 abstract "The energies of combustion of crystalline glycylglycine and dl-alanyl-dl-alanine were determined using oxygen bomb calorimetry. The molar enthalpies of combastion ΔcH°m at T = 298.15 K were calculated from the experimental results for glycylglycine and dl-alanyl-dl-alanine in the crystalline state and were found to be −(1969.67 ± 1.26) kJ · mol−1 and −(3267.47 ± 1.84) kJ · mol−1, respectively. For both combustion reactions, the enthalpies are based upon the amount of CO2 produced. The corresponding molar enthalpies of formation ΔfH°m for glycylglycine and dl-alanyl-dl-alanine are −(747.68 ± 1.29) kJ · mol−1 and −(807.32 ± 1.87) kJ · mol−1, respectively. Values were also derived for the contribution to ΔfH°m of the glycine {−CH2NHCO−} and dl-alanine {−CH(CH3)NHCO−} repeating units for peptides in the crystalline state at T = 298.15 K." @default.
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- W2055000056 date "1992-12-01" @default.
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- W2055000056 title "Enthalpies of combustion of glycylglycine and dl-alanyl-dl-alanine" @default.
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- W2055000056 doi "https://doi.org/10.1016/s0021-9614(05)80272-1" @default.
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