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- W2055040669 abstract "Abstract The rate of the reaction CH2+N2 is modeled by transition state (RRKM) theory in order to evaluate its importance as a candidate precursor for so-called “prompt” NO formation in flame fronts. The transition state parameters are based on the best available thermochemical and kinetic data, assuming a “tight” complex. The rate constant predicted by the model for the triplet ground state has the form k = 8 × 10−12: exp(− 18,000/T) cm3/molecule-sec. Nearly identical results were obtained for the singlet first excited state, assuming a zero activation energy for the addition of CH2 to N2. These rate constants are a factor of 675-85 smaller than the experimental values reported for the reaction CH + N2 in the temperature range 1500-2000 K. Thus the reaction of CH2 with N2 is unlikely to be an important precursor of prompt NO formation." @default.
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- W2055040669 date "1987-01-01" @default.
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- W2055040669 title "On the Importance of the Reaction CH<sub>2</sub>+N<sub>2</sub>→HCN+NH as a Precursor for Prompt NO Formation" @default.
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- W2055040669 doi "https://doi.org/10.1080/00102208708960318" @default.
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