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- W2055043737 abstract "A clinically important natural isoquinoline alkaloid, berberine, was used as a fluorescent probe to study the encapsulation of 1-alkyl-3-methylimidazolium (CnMIm+) type ionic liquids in 4-sulfonato-substituted calix[4]arene (SCX4) and calix[6]arene (SCX6) at pH 2. Addition of ionic liquids to the aqueous solution of berberine−SCXn inclusion complexes brought about considerable fluorescence intensity diminution due to the extrusion of berberine from the macrocycle into the aqueous phase by the competitive inclusion of CnMIm+ cation. The lengthening of the aliphatic side chain of the imidazolium moiety diminished the equilibrium constant of complexation with SCX4, but enhanced the stability of SCX6 complexes. Larger binding strength was found for SCX4." @default.
- W2055043737 created "2016-06-24" @default.
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- W2055043737 date "2009-07-01" @default.
- W2055043737 modified "2023-10-15" @default.
- W2055043737 title "Inclusion complex formation of ionic liquids with 4-sulfonatocalixarenes studied by competitive binding of berberine alkaloid fluorescent probe" @default.
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- W2055043737 doi "https://doi.org/10.1016/j.cplett.2009.06.055" @default.
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