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- W2055092014 abstract "Hydrochlorination of cis- and trans-1 -phenylpropenes and their ring-substituted derivatives (p-CH3O, p-CH3, and p-Cl) has been studied in acetic acid at 16–35°C. 1-Phenylpropene gave predominantly a cis-adduct while the p-CH3O derivative yielded a non-stereospecific product. For the p-CH3O and p-CH3 derivatives, the cis isomer was found to be more reactive than the corresponding trans isomer, while for the p-Cl derivative the opposite relative reactivity was observed. The origins of these cis/trans reactivities have been discussed in terms of the electronic and steric effects on stability of the solvated transition state." @default.
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- W2055092014 date "1974-06-01" @default.
- W2055092014 modified "2023-09-23" @default.
- W2055092014 title "The Relative<i>cis/trans</i>Reactivity in the Hydrochlorination of 1-Arylpropenes" @default.
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- W2055092014 doi "https://doi.org/10.1246/bcsj.47.1477" @default.
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