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• W2055093764 abstract "Performance of inverted bulk-heterojunction solar cells with widely used tris(8-quinolinolate)aluminium(III) (Alq3) is compared with a series of novel zinc-benzothiazole (Znb2) derivatives as buffer layer. The devices including a Znb2 thin layer between the poly(3-hexylthiophene) (P3HT):C61-butyric acid methyl ester (PCBM) blend and the Au anode show a significant improvement in the power conversion efficiency (η), which is enhanced by 30% compared to Alq3cells. Moreover, by combining both Alq3 and Znb2 in the device as a double buffer layer prior to the metal electrode deposition, the efficiency improves by 40%. The reasons for the enhanced performance of Znb2 cells are attributed to the efficient charge transport and electron/exciton blocking properties. Furthermore it is expected that the deposition of Znb2 modifies the Au work function to facilitate the hole transport and collection at the anode, and encapsulate the P3HT/PCBM blend during the electrode deposition. The presented photovoltaic cells also show high stability in ambient air conditions over a period of 245 days, which evidences the need of Znb2 buffer layers for long-term device durability." @default.
• W2055093764 created "2016-06-24" @default.
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• W2055093764 date "2011-01-01" @default.
• W2055093764 modified "2023-09-27" @default.
• W2055093764 title "Enhanced performance and stability of inverted organic solar cells by using novel zinc-benzothiazole complexes as anode buffer layers" @default.
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• W2055093764 doi "https://doi.org/10.1039/c1jm13256c" @default.
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