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- W2055102521 abstract "Abstract A novel atrazinium selective membrane sensor consisting of an atrazine phosphomolybdate ion-pair complex dispersed in a PVC matrix plasticized with dioctylphthalate is described and electrochemically evaluated under static and hydrodynamic modes of operation. The sensor is incorporated in a flow-through sandwich cell and used as a detector for flow injection determination of atrazine herbicide. The intrinsic characteristics of the detector in a low dispersion manifold is determined and compared with those of a conventional-shaped sensor. In a phosphate buffer of pH 5, the detector exhibits a rapid near-Nernstian response (52.3 mV/decade) for atrazinium cation over the concentration range 10−2 - 10−5 M. Concentrations as low as 0.3μg/ml of atrazine can be detected with an average recovery of 98.3% (mean standard deviation 0.6%), and the sample input rate is 60 sample per hour. The sensor is used for determining atrazine in herbicide formulations, and in extracts of water and soil. No interferences..." @default.
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- W2055102521 date "1998-03-01" @default.
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- W2055102521 title "Flow Injection Potentiometric Determination of Atrazine in Herbicide Formulations" @default.
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- W2055102521 doi "https://doi.org/10.1080/00032719808002817" @default.
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