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- W2055102751 abstract "A novel heterogeneous method for efficient oxygenation of olefins to epoxides and saturated hydrocarbons to the related ketones using tetrabutylammonium peroxomonosulfate (n-Bu4NHSO5) in neat water catalyzed by Fe(TPP)Cl and Fe(TDCPP)Cl complexes as water-insoluble catalysts has been developed. The oxidation system proceeds well in the absence of organic co-solvents and surfactants. The electron-deficient Fe(TDCPP)Cl catalyst could easily be recycled and reused without loss of activity and the oxidant's by-product (n-Bu4NHSO4) could also be recycled." @default.
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- W2055102751 date "2011-03-01" @default.
- W2055102751 modified "2023-10-17" @default.
- W2055102751 title "A novel strategy for clean and selective oxygenation of hydrocarbons with n-Bu4NHSO5 in neat water catalyzed by recyclable water-insoluble iron (III) tetraphenylporphyrins" @default.
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- W2055102751 doi "https://doi.org/10.1016/j.catcom.2011.01.013" @default.
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