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- W2055109245 abstract "The substitution of Ga3+ into the Jahn−Teller distorted, antiferromagnetic perovskites LaMnO3 and NdMnO3 strongly affects both the crystal structures and resulting magnetic ordering. In both compounds the Ga3+ and Mn3+ cations are disordered over the six coordinate sites. La2GaMnO6 is a ferromagnetic insulator (Tc = 70 K); a moment per Mn cation of 2.08(5) μB has been determined by neutron powder diffraction at 5 K. Bond length and displacement parameter data suggest Jahn−Teller distortions which are both coherent and incoherent with the Pnma space group symmetry of the perovskite structure (a = 5.51122(4) A, b = 7.80515(6) A, c = 5.52947(4) A) at room temperature. The coherent distortion is strongly suppressed in comparison with the parent LaMnO3 phase, but the displacement ellipsoids suggest that incoherent distortions are significant and arise from local Jahn−Teller distortions. The preparation of the new phase Nd2GaMnO6 has been found to depend on sample cooling rates, with detailed characterization n..." @default.
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- W2055109245 date "2010-05-26" @default.
- W2055109245 modified "2023-09-25" @default.
- W2055109245 title "ChemInform Abstract: Control of Magnetic Ordering by Jahn-Teller Distortions in Nd2GaMnO6 and La2GaMnO6." @default.
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- W2055109245 doi "https://doi.org/10.1002/chin.200121010" @default.
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