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- W2055114580 abstract "Ni(II), Pd(II) and Pt(II) complexes of O-ethylphenyldithiophosphate, [S2P(OEt)C6H5]−, crystalize as trans products although the MS4 coordination about the metal is square planar. Isomerization occurs in organic solvents to produce essentially (by NMR) equal amounts of cis and trans isomers. The rate of isomerization decreases Ni ⪢ Pd > Pt. The isomerization of trans-Pd[S2P(OEt)C6H5]2 has been studied quantitatively in various solvents. In benzene Ea ≅ 18 kcal/mole with ΔHDG ≅ 18 kcal/mole and ΔS‡ ≅ −17 e.u. The rearrangement appears to be solvent assisted. CS2 increases the isomerization rate by a factor of five. The X-ray crystal structures of the Pd(II) and Pt(II) complexes are described in detail. The MS distances are approximately 2.34 Å in both complexes, although the space groups are different." @default.
- W2055114580 created "2016-06-24" @default.
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- W2055114580 date "1981-01-01" @default.
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- W2055114580 title "Sulfur chelates 36. Structural characterization of the Trans isomers of the O-ethylphenyldithiophosphonates of Pd(II) and Pt(II), M[S2P(OC2H5)C6H5]2. Cis-Trans isomerization of the planar Pd(II) complex" @default.
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- W2055114580 doi "https://doi.org/10.1016/s0020-1693(00)90064-1" @default.
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