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- W2055123253 abstract "Abstract The nature of silver cyanide complexes has been studied at constant ionic strength by the potentiometric method. Measurements have been carried out in the range 1:1 to 1:20 (Ag+:CN−) and for Ag+ concentrations between 0·005 and 0·1 M. Two inflexions corresponding to AgCN and Ag(CN)2− have been observed at the ratios 1:1 and 1:2. The formation of Ag(CN)43− and Ag(CN)42− has been found to occur gradually. The existence of Ag(CN)33− has been proved. Stability constants have been calculated from the intercept of the linear relation between the formal potential of the complex and the logarithm of CN− concentration. The number of cyanide ligands has been estimated from the slope of this relation. The results indicate the possible occurrence of a mixture of the 3 and 4-coordinated complexes at high cyanide concentrations." @default.
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- W2055123253 date "1967-06-01" @default.
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- W2055123253 title "Potentiometric study of silver cyanide complexes" @default.
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- W2055123253 doi "https://doi.org/10.1016/0013-4686(67)85032-1" @default.
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