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• W2055126996 endingPage "6388" @default.
• W2055126996 startingPage "6382" @default.
• W2055126996 abstract "Abstract Shiny black, air‐insensitive crystals of tellurium‐rich one‐dimensional coordination polymers were synthesized by melting a mixture of the elements with TeCl 4 . The compounds [Ru(Te 9 )](InCl 4 ) 2 and [Ru(Te 8 )]Cl 2 crystallize in the monoclinic space group type C 2/ c , whereas [Rh(Te 6 )]Cl 3 adopts the trigonal space group type R c . In the crystal structures, linear, positively charged [M m+ (Te n ±0 )] (M=Ru, m =2; Rh, m =3) chains run parallel to the c axes. Each of the uncharged Te n molecules ( n =6, 8, 9) coordinates two transition‐metal atoms as a bridging bis‐tridentate ligand. Because the coordinating tellurium atoms act as electron‐pair donors, the 18‐electron rule is fulfilled for the octahedrally coordinated transition‐metal cations. Based on DFT calculations, the quantum theory of atoms in molecules (QTAIM) and the electron localizability indicator (ELI) provide insight into the principles of the polar donor bonding in these complexes. Comparison with optimized ring geometries reveals substantial tension in the coordinating tellurium molecules." @default.
• W2055126996 created "2016-06-24" @default.
• W2055126996 creator A5010808682 @default.
• W2055126996 creator A5056084527 @default.
• W2055126996 creator A5065140599 @default.
• W2055126996 creator A5091614245 @default.
• W2055126996 date "2011-04-21" @default.
• W2055126996 modified "2023-10-18" @default.
• W2055126996 title "Neutral Tellurium Rings in the Coordination Polymers [Ru(Te₉)](InCl₄)₂, [Ru(Te₈)]Cl₂, and [Rh(Te₆)]Cl₃" @default.
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