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- W2055128320 abstract "Reflection mode high energy electron diffraction (RHEED) has been used in an ultra high vacuum environment to study the initial stages of the oxidation of (100) and (110) tungsten single crystal surfaces.On exposing the (110) tungsten surface to oxygen at temperatures below 1025°K, nuclei of tungsten trioxide grow. The epitaxial relationships are metal (110)//oxide (111) and metal [001]// oxide [110]. The nuclei may be removed by heating the surface in a good vacuum to 100 °K. The growth of nuclei on the (100) tungsten surface is complicated by the faceting of that surface. On unfaceted surfaces tungsten trioxide nuclei form after small exposures of oxygen, but again only at temperatures below 1025 °K. On faceted surfaces much larger doses of oxygen are required. In both cases the epitaxial relationships are metal (100)//oxide {100} ± 9° and metal [011]//oxide ± 7.5°. It is shown that the (100) W/oxide system can be described in terms of the metal (110)/oxide system." @default.
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- W2055128320 date "1971-05-01" @default.
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- W2055128320 title "Rheed studies of the initial stages of the oxidation of tungsten" @default.
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- W2055128320 doi "https://doi.org/10.1016/0022-0248(71)90209-0" @default.
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