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- W2055133261 abstract "The reaction of CdCl(2), 18-crown-6 and KI in water yields the title coordination polymer, [{K(C(12)H(24)O(6))}(2)Cd(2)I(6)](n). The potassium ion lies approximately in the plane of the crown ether, coordinated by all six crown ether O atoms and also by an iodide anion bound to a cadmium atom. A C atom of the crown ether is disordered over two positions with site occupancies of 0.77 (2) and 0.23 (2). Two K(18-crown-6)(+) units are linked by inversion symmetry, forming a [bis-(μ(2)-18-crown-6)dipottasium] system with approximately square-planar K(2)O(2) units. Inversion symmetry also generates the Cd(2)I(6) fragment and the polymeric system is extended along the c axis by the formation of K-I-Cd bridges." @default.
- W2055133261 created "2016-06-24" @default.
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- W2055133261 date "2013-01-31" @default.
- W2055133261 modified "2023-10-06" @default.
- W2055133261 title "<i>catena</i>-Poly[[bis(μ<sub>2</sub>-1,4,7,10,13,16-hexaoxacyclooctadecane)dipotassium]-μ<sub>2</sub>-iodido-(iodidocadmium)-di-μ<sub>2</sub>-iodido-(iodidocadmium)-μ<sub>2</sub>-iodido]" @default.
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- W2055133261 doi "https://doi.org/10.1107/s1600536813002274" @default.
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