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- W2055142891 abstract "A polystyrene−poly(ethylene-alt-propylene) diblock copolymer, S/EP 7/13, exhibits a thermoreversible mesophase transition between low-temperature hexagonally perforated lamellae (HPL) and high-temperature hexagonally packed cylinders (C). The transformation process is accompanied by a 6% change in the principal spacing, yet oriented specimens retain their macroscopic orientation through the transition. The C → HPL transformation proceeds on a time scale of tens of minutes, at a rate which initially increases rapidly with undercooling relative to the order−order transition temperature. At deep undercoolings, the transformation rate slows due to a reduction in molecular mobility. By contrast, the HPL → C transformation occurs nearly 2 orders of magnitude more rapidly, a difference which is suggested to reflect the nature of the dominant fluctuation modes for the two structures." @default.
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- W2055142891 date "2005-07-13" @default.
- W2055142891 modified "2023-09-30" @default.
- W2055142891 title "Dynamics of a Thermoreversible Transition between Cylindrical and Hexagonally Perforated Lamellar Mesophases" @default.
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- W2055142891 doi "https://doi.org/10.1021/ma050953n" @default.
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