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• W2055144468 abstract "In vivo administration experiments using stable (13C) and radio (14C) labeled precursors established that the optically active 8-2' linked lignans, (-)-cis-blechnic, (-)-trans-blechnic and (-)-trans-brainic acids, were directly derived from L-phenylalanine, cinnamate, and p-coumarate but not either from tyrosine or acetate. The radiochemical time course data suggest that the initial coupling product is (-)-cis-blechnic acid, which is then apparently converted into both (-)-trans-blechnic and (-)-trans-brainic acids in vivo. These findings provide additional evidence for vascular plant proteins engendering distinct but specific phenolic radical-radical coupling modes, i.e., for full control over phenylpropanoid coupling in vivo, whether stereoselective or regiospecific." @default.
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• W2055144468 date "2003-02-01" @default.
• W2055144468 modified "2023-09-25" @default.
• W2055144468 title "[13C]-Specific labeling of 8–2′ linked (−)-cis-blechnic, (−)-trans-blechnic and (−)-brainic acids in the fern Blechnum spicant" @default.
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• W2055144468 doi "https://doi.org/10.1016/s0031-9422(02)00540-x" @default.
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