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- W2055145940 abstract "• p-NP reduction is the best at pH 7.6 by Fe(II) species in chloride medium. • Sulfate and its dosage have markedly inhibitory effect on p-NP reduction. • Chloride and its dosage have no obvious effect on p-NP reduction. • Sulfate has selective adsorption on Fe hydroxide. • Sulfate can form surface complexes on Fe hydroxide. Electron exchange between aqueous Fe(II) and structural Fe(III) of iron minerals has been illustrated for understanding the reduction of nitroaromatic compounds (NAC). However, factors influencing Fe(II)-induced the reduction of NAC still remain elusive. In this paper, p-nitrophenol (1.5 mM) was selected to explore the effects of pH, the stabilizing ligands (Cl − , SO 4 2− ) of ferrous ions and the extra addition of iron hydroxide on the reduction of NAC via Fe(II) species. The results indicate that the reduction degree of is much lower in SO 4 2− medium than that in Cl − medium at pH 7.6. p-Nitrophenol reduction increased in SO 4 2− medium and slightly decreased in Cl − medium when Fe hydroxide was extra added. Cl − strength (0.01–0.1 mol L −1 ) has no obvious effect on p-NP reduction. SO 4 2− species and its dosage have markedly inhibitory effect on p-NP reduction due to the selective adsorption of SO 4 2− and the formation of sulphated surface complexes on the fresh Fe hydroxide." @default.
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- W2055145940 date "2013-12-01" @default.
- W2055145940 modified "2023-10-16" @default.
- W2055145940 title "Reductive transformation of p-nitrophenol by Fe(II) species: The effect of anionic media" @default.
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- W2055145940 doi "https://doi.org/10.1016/j.jhazmat.2013.10.013" @default.
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