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• W2055145957 abstract "1-(p-Substituted benzyl)-2,4,6-triphenylpyridinium cations react with β -diketone anions by mechanisms which depend on the para-substituent. The p-methoxybenzyl derivative undergoes SN1 displacement yielding O- and C-benzylated products. The pnitrobenzyl compound reacts by a chain radicaloid mechanism and gives high yields of C-pnitrobenzylated diketones. The parent benzyl compound forms some C- and some O-benzylated products, together with bibenzyl, probably by a radical chain reaction which was suppressed by radical traps." @default.
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• W2055145957 date "1990-01-01" @default.
• W2055145957 modified "2023-10-16" @default.
• W2055145957 title "C-alkylation of β diketones with benzylpyridinium salts. Evidence for chain radical mechanisms" @default.
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• W2055145957 doi "https://doi.org/10.1016/s0040-4020(01)87840-6" @default.
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