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• W2055147890 abstract "Abstract 2-(Benzo-d-thiazol-2-yl)quinoline (BTQ) was synthesized and tested for its use as a fluorescent chemosensor for Hg2+. The metal-ion recognition of BTQ was investigated by adding several metal ions (M2+) to a solution of BTQ in acetonitrile. The shape and intensity of the fluorescence spectra did not change upon addition of several metal ions, except for Hg2+ and Cu2+. The time-dependent density functional calculations were carried out on BTQ and BTQ–M2+ complexes (M = Zn, Cd, and Hg) to clarify their spectroscopic properties. The results of the calculation showed that the energy levels of the excited singlet and triplet states are similar in Zn2+ and Cd2+ complexes, whereas the Hg2+ complex has lower transition energy. The character of their excited states was also different between zinc and cadmium complexes with the mercury complex." @default.
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• W2055147890 date "2011-04-01" @default.
• W2055147890 modified "2023-09-30" @default.
• W2055147890 title "TD-DFT study on the fluorescent chemosensor for Hg2+, 2-(Benzo-d-thiazol-2-yl)quinoline" @default.
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• W2055147890 doi "https://doi.org/10.1016/j.molstruc.2011.02.002" @default.
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