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- W2055168022 abstract "Abstract A truly miscible ternary miscible blend consisting of poly(ϵ‐caprolactone) (PCL), poly(phenyl methacrylate), and poly(benzyl methacrylate) (PBzMA) was discovered. The three‐polymer blend system was completely miscible within the entire composition range at ambient temperature up to about 150 °C, and ternary phase diagrams at increasing temperatures were characterized and interpreted. A ternary‐interaction model based on the modified Flory–Huggins expression was used to describe the phase diagrams with the individual binary interaction strengths. The model fitted well with the experimental‐phase diagram for the ternary blend system at T = 250 °C, where the binary PCL‐PBzMA blend system is on the critical points of phase separation. Interpretation of discrepancy between the model and experimental at other temperatures was handled with an empirical approach. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 747–754, 2002" @default.
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- W2055168022 date "2002-03-01" @default.
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- W2055168022 title "Binary versus ternary interactions in a completely miscible three-polymer blend system: Poly(?-caprolactone) with two different methacrylic polymers" @default.
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- W2055168022 doi "https://doi.org/10.1002/polb.10130" @default.
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