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- W2055175197 abstract "EPR spectra of the nitroxide radical 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) are reported in super critical and in liquid n-hexane and ethanol for 25−200 bar and 295−600 K. At low radical concentration (<10-5 M) the line width is controlled by the spin-rotation interaction and is quantitatively predicted by liquid-phase theory for solvent densities ρ greater than the critical density ρc. Deviations at lower densities are assigned to clustering effects and the crossover to gas-phase behavior. Rate constants for Heisenberg spin exchange ([TEMPO] > 10-3 M) up to 580 K are also reported. They again follow liquid-phase theory for ρ > ρc. Deviations at low densities may be explained by a gas-phase behavior without clustering effects." @default.
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- W2055175197 date "1998-01-01" @default.
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- W2055175197 title "Free Radical Motion in Super Critical Fluids Probed by EPR Spectroscopy" @default.
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- W2055175197 doi "https://doi.org/10.1021/jp972346a" @default.
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